Kinetic study of the conversion of cis-2-butene to deuterium over a Pd/Fe3O4 model catalyst.
The isomerization of cis-2-butene and trans-2-butene is catalyzed by acid and ion-exchange smectite-type clays.
cis-2-butene is a natural product present in Echemi.com, Echemi, and other organisms for which data is available.
Photolysis of cis-2-butene and its implications for radiation chemistry.
Cis-2-butene was studied in the gas phase at room temperature for direct photolysis at 1849 Å and mercury photoreaction at 2537 Å. It can be considered that the former forms an excited singlet state of cis-2-butene, and the latter forms an excited triplet state of cis-2-butene. The latter mainly produces trans-2-butene, while the former mainly produces decomposition products (such as hydrogen, methane, ethane, ethylene, propylene, etc.). The formation rate of all products in the former is independent of pressure, while the formation rate of all products except trans-2-butene in the latter decreases rapidly with the increase of initial pressure. However, the formation rate of trans-2-butene in the latter gradually increases with increasing initial pressure until it becomes constant above 100 mmHg. By comparing the pressure dependence and product distribution of these two reactions with the radiolysis results of liquid cis-2-butene, it can be concluded that the excited triplet state of cis-2-butene mainly contributes to the reaction The formation of cis-2-butene is in radiolysis, while the excited singlet state of cis-2-butene mainly contributes to the decomposition products.
Kinetic study of the conversion of cis-2-butene to deuterium over a Pd/Fe3O4 model catalyst.
The isomerization of cis-2-butene and trans-2-butene is catalyzed by acid and ion-exchange smectite-type clays.
